Š้‹ฦ๎•๑„‚ฒˆฅŽA„ Silicon Nitride Prepared by the SiH3-NH3 Reaction with Catalysts

 Silicon Nitride Prepared by the SiH?-NH? Reaction with Catalysts


Shumpei YAMAZAKI, Kunihiko WADA and Ichiro TANIGUCHI

The application of catalysts to chemical vapor deposition process to activate reactive species is shown effective in improving electrical properties of Si]Si3N4 systems. NFB  of the Si]Si3N4 system prepared by the catalytic method is about one tenth of NFB of those prepared by the conventional method.@ The catalysts of NiO and Pt are applied to the ammonia and silane respectively.@The catalysis seems to be effective to reduce the deposition temperature by about@100ŽD@The density of the interface states is about 1~1011 cm]2 and the peak energy levels of donor and@acceptor@states are 0.43eV@and -0.47eV respectively. Injection type hysteresis loops are always observed in@the in]version region of both p- and n-type samples at a low temperature. The hysteresis is proportional to the film thickness and is independent of the preliminary treatments.

w1970”N Japanese Journal of Applied Physics. ‚ๆ‚่”ฒˆx


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